NEW! UWM Biomedical Engineering Degree

The Chemist's Notebook to Stoichiometry

By: Andrew Kasperkiewicz

BOOK 1: A-Z Chemical list, Formulas, syntheses, and information.

https://www.google.com/search?q=polish+translator&rlz=1C1CHBF_enUS742US742&oq=polish+translator&aqs=chrome..69i57j0l5.6932j0j7&sourceid=chrome&ie=UTF-8

https://patents.google.com/patent/US2868793A/en

https://www.webqc.org/balance.php

A

Acepromazine: C19H22N2OS maleate used in veterinarian medicine

Acetomenophen: (aceto amino phenol) CH3CONHC6H4OH. 1C+1CO+1C6H5OH 39g C + 69g CO + 235g C6H5OH + 42g NH3 = 377g CH3CONHC6H4OH
Reaction type: synthesis or Balanced equation:
2 CO + NH3 + C6H6 = CH3CONHC6H4OH
Reaction type: synthesis

Aldol: CH3CHOHCH2CO. 4CH3CHO=2CH3CHOHCH2CO+H2 reaction type decomposition

Amitrypytline: C20H23N for pain and depression 13C+NH4OH+C7H16+H2 +HCl =C20H23N*HCl Note: heptane is C7H16. Balanced equation:
97 C + 8 NH4OH + 9 C7H16 = 8 C20H23N + 4 O2

Amobarital: C3H7NO2+C4H4O3N2=C11H18N2O3 (urethane plus barbituric acid)

Amphetamine: 1g C8H11N+.1g C+.0167g H2=1.25g C6H5CH2CH(NH2)CH3 Benzyl + ? + Methyl. Phenethylamine plus coal plus hydrogen

Antipyrine:(CH3)2(C6H5)C3HN2O. For fever and used with benzocaine.

Ativan: C15H10Cl2N2O2. 2C6H5Cl+3C+2NH4OH=C15H10Cl2N2O2+5H2 Balanced equation:
187g 2 C6H5Cl + 30g 3 C + 58g 2 NH4OH = 267g C15H10Cl2N2O2 + 8.4g 5 H2

{note: substitute Bromine for Chlorine may result in new Benzodiazapine drug}

B

Bamboozle: NH4OH+NH2COOH+C2H5OH+ {terpenes/oils/ammonia [LIST EVERYTHING]}. Carbamic Acid is NH2COOH. Made by bubbling CO2 thru NH4OH, mix with carbonate esters such as phenethylamine carbonate. See meprobamate.

Barbital: diethylbarbituric acid. C8H12N2O3. H5C2OC2H5+C4H4O3N2=C8H12N2O3+H2O barbituruc acid C4H4N2O3 (polymerization catalyst)

Benzocaine: C6H4NH2COOC2H5. NH3+C6H6+C2H5OH=C6H4NH2COOC2H5 or C6H6+NH3+CO2 (reaction type synthesis) or xylene +CO2+NH4OH or commonly sold as hydrochloride salt, price as of 2017: $40 per Kilogram. Balanced equation:
4 C6H6 + 3 NH3 + 3 CO2 = 3 C6H4NH2COOC2H5
Reaction type: synthesis

C6H6+2C2H5Cl+CO2=C6H4NH2COOC2H5+Cl2 (Benzene plus ethyl chloride plus carbon dioxide)

Benzyl Piperazine: C11H16N2 According to Shulgin, dose 20-100mg (PIHKAL). piperidine (CH2)5NH [from hydrolysis of piperine treated with alkali from piper nigrum (black pepper)]

Buticaine Sulfate: (C18H30N2O2)2*H2SO4 local anesthetic for mucous membranes. Butane: C4H10

C

Chloral Hydrate: CCl3*2CH(OH)2. C2H5OH+3Cl2= CCl3*2CH(OH)2 freeze.C2H3Cl3O2 Balanced equation:
2 C2H5OH + 3 Cl2 + O2 = 2 C2H3Cl3O2 + 3 H2

Chlorcyclizine: C18H21ClN2 antihistamine for allergies

Chlorothiazide: C7H6ClN3O4S2 for heart failure, edemas, and hypertension.

Chloropromazine: C17H20N2S*HCl. 2C+C12H9N+C3H7+2NH3+HCl=C17H20N2S*HCl+H2 [S????] Promethazine+____? = phenothiazine

Clonidine: C9H9Cl2N3 eases narcotic withdrawl. Dosage: 100 micrograms – 2.4 milligrams 9C+3NH4OH+Cl2=C9H9Cl2N3+3H2O Balanced equation:
30g 9 C + 29g 3 NH4OH + 19g Cl2 = 64g C9H9Cl2N3 + 15g 3 H2O.

9 C + 3 NH3 + Cl2 = C9H9Cl2N3
Reaction type: synthesis

Cocaine: C17H21NO4*HCl hydrochloride salt.34C+2NH4OH+16H2O2=2C17H21NO4+13O2 Balanced equation:
30g 34 C +5.1g 2 NH4OH + 2.4g 16 H2 + 7g 3 O2 = 44g 2 C17H21NO4
Reaction type: synthesis

Codeine: C18H21NO3*H2O. Balanced equation:
15 C + 6 H2O + 2 NH3 + 3 C6H5CH3 = 2 C18H21NO3
Reaction type: synthesis base.

Compazine: C28H32ClN3S nauisa/anxiety. C+H2+HCl+NH4OH+H2SO4=C28H32ClN3S (10 g 56 C + 3.1g 6NH4OH + 1.08g 2HCl +2.92g 2H2SO4) Balanced equation:
56 C + 14 H2 + 2 HCl + 6 NH4OH + 2 H2SO4 = 2 C28H32ClN3S + 7 O2

Cyclazocine: C18H25NO blocks effects of morphine, it is a non-addictive pain killer. 3C6H6+NH3+H2O+H2=C18H25NO

D

DHEA: (di hydro epiandrosterone)

Diazapam: C16H13CLN2O. 30g C+28g C6H5Cl+8.5g 2NH3+4.5g H2O=71.5 g C16H13CLN2O.

10 C + C6H5Cl + 2 NH3 + H2O = C16H13ClN2O
Reaction type: synthesis

Dilatin: C15H11N2O2. 3H2CO3+C6H5N:N:C6H5=C15H11N2O2+H2O2.

Diethylbarbital: C2H5OC2H5O+C4H4N2O3=C8H12N2O3. toxic. ether plus barbituric acid.

Diosgenin: C27H42O3. steroid in yams. It is used to synthesize hormones. ex: progesterone, yams good for pregnancy. Starting point for hormone synthesis.

Dimethyltryptamine: C12H16N2. 30g 28C+25g 8NH4OH+33g 5H5C2OC2H5=67g 4C12H16N2+20g 13H2O Balanced equation:
28 C + 8 NH4OH + 5 H5C2OC2H5 = 4 C12H16N2 + 13 H2O [note MgSO4 soaks up excess ether]. Seen as fumarate salt, or free based. Stored in freezer to crystalize from naptha, washed with water and sodium carbonate. .5 g C+.4g NH4OH+.55g H5C2OC2H5=1.12 DMT+.35 H2O

DMSO: (CH3)2SO hypoallergenic solvent. H2SO4+CH3OH=DMSO+H2O+O2.

Dopamine: C8H11NO2 neurotransmitter C8H11N+O2=C8H11NO2 [bubble compressed air thru phenethylamine hydrochloride dissolved in water, using baking soda, vinegar, a hose with two two liter bottles with holes in the caps {gas generator}].

E

EDTA: C10H16N2O8 prevents blood coagulation during metal poisoning. acetic acid plus ethylene plus compressed air (nitrous oxide). 4CH3COOH+H2C:CH2+N2O{or2NH3} =C10H16N2O8+H2O+H2. (Note: H gets replaced by acetic acid I believe)

Ephedrine: C10H15NO made synthetically. Balanced equation:
30g 11 C + 62g 3 C6H5CH3 + 15g 4 NH3 + 41g 4 C2H5OH = 4 C10H15NO
Reaction type: synthesis

Epinephrine: C10H15N local anesthetic potentiator. C+C6H5CH3+NH4OH+C2H5OH=C10H15N+H2O+H2. see methamphetamine synthesis minus HCL.

Ethyl Chloride: C2H5Cl local anesthetic. C2H5OH+HCl (catalyst: in the prescence of zinc chloride) =C2H5Cl. NOTE: possible starting point for sleeping pill synthesis; example: C+C2H5Cl+NH4OH=C2H10NClO [C+C2H10NOCl]

Ethylene: H2C:CH2 made by dehydration of, ethanol, or cracking natural or coal gas. CH4 methane polymer cracked equals CH2+H2. Cracking is done by heat and pressure or catalysts ie, breaking hydrocarbons into lighter ones; example petroleum to gasoline. can dehydrate alcohol by calcium chloride or other dehydrating methods.

Eucaine: alpha Eucaine: C19H27NO4. 30g 14C+15g (CH2)5NH+12g 4H2O+1.5g 4H2=59.5g C19H27NO4. Balanced equation:
14 C + (CH2)5NH + 4 H2O + 4 H2 = C19H27NO4
Reaction type: synthesis

Beta Eucaine: C15H21NO2 10C+(CH2)5NH+2H2O+3H2=C15H21NO2 0.7 g 10 C +0.5 g (CH2)5NH + 0.2g 2 H2O + .02g 3 H2 = 1.45g C15H21NO2
Reaction type: synthesis. see piperidine.

10g C17H19NO3 + 0.63g H2O = 2.98g (CH2)5NH + 7.65g C12H10O4 [catalyst NaOH/HCl]
Reaction type: double replacement

Synthesis from black pepper: 1. 150 g black pepper in 300 ml isopropyl. 2. wash with 100 ml iso/H2O and filter through boxer shorts. 3. collect liquid and discard grounds. 4. add one liter of water saturated with baking soda, baking soda (try sodium acetate from spent club soda gas generator) helps salt out the piperine as piperine is insoluble in water. once piperine precipitates, filter thru boxer shorts, and keep the solids. KOH and Acetone rids resins and filters/evaporates to piperine. wash the powder with water to rid the isopropyl, and filter thru paper towel. dry the powder (crude piperine). Add piperine to lye and HCl mixture to form piperidine and piperic acid. or add ammonia hydroxide and heat to white powder forms. Activate charcoal by adding HCl to charcoal and filter (see dichloromethane). Can use hydrochloric acid plus aluminum to generate hydrogen gas. use tantalum electrodes from old school televisions or other old electronic capacitors. Or graphite pencil lead electrodes can be used or a 2-amp electrolysis using a cut phone charger, or two bridged 9-volt batteries with alligator clips and copper wire. NOTE: Both Eucaine isomers are anologes of cocaine.

F

Formaldehyde: HCHO. CH3OH=HCHO+H2O. add road salt to methanol (dehydrate with calcium chloride.) Note: nitric acid is an oxidizer, and calcium chloride is a dehydrating agent.

G

Gama Hydroxy Butal (GHB): C4H8O3. CH3CH2CH2COOH+H2O2=C4H8O3+5H2O. Butric acid is in rancid butter and sweat. Balanced equation:
2.6g CH3CH2CH2COOH + 1g H2O2 = 3g C4H8O3 + .5g H2O
Reaction type: double replacement

Gentisic acid: C6H3(OH)2COOH. sodium salt used as an analgest + trypsin

Glycerol: C3H5(OH3). hydrolysis of fats and oils.

H

Halopiperidineol: C21H23ClFNO2 tranqulizor/tourettes. 3C+3C6H6+NaF+NaCl+NH3=C21H23ClFNO2+2NaOH

Heroine: C17H17NO(C2H3O2)2 morphine is a 15 mg dose for reference. [cyclazocine is for blocking effects of heroine]. 8C+H2O2+C2H5OH+NH3+H2O+2Na(CH3COO) =C17H17NO(C2H3O2)2+H2+2NaOH

Hordenine: C10H15NO. Barley + 70% alcohol or water?? Sprouted/?

Hormone Synthesis: aldosterone: C21H28O5, androstenedione: C19H26O2 precursur to

testosterone, androsterone:C19H30O2, corticosterone; C21H30O4, cortisone: C21H28O5, oxytocine: C43H66N12S2 stimulates uterus and milk, tachysterone: C28H44O, tamoxifen: C23H37NO10, thyroxine: C15H11I4NO4. SEE: testosterone

Hydrocodone: C18H21NO3 synthesised from codeine or possibly thebaine. Hydrocodone bitartrate chemical formula: C22H27NO9 note: C4H5O6 is hydrogen tartrate from cream of tartar.

I

Ibogaine: C20H26N2O extract of dogbane family plants. Tannins precipitate alkaloids, oak bark has tannins. See vinblastine periwinkle alkaloids.

Ibuprophen: (isobutyl + propionic acid + phenol) C13H18O2

Imipramine: C19H24N2 antidepressant. C+3C6H6+2NH3=C19H24N2

Indol acetic acid: C10H9NO2 root hormone promotes growth.

J

K

Ketamine: C13H16ClNO*HCl. 56 C6H5CH3 + -33 CH3COCH3 + 24 NH4Cl + 19 H2CO3 = 24 C13H16ClNO
Reaction type: synthesis [toluene + acetone + hydrochloric acid + carbon dioxide + water + ammonia]. Balanced equation:
56 C6H5CH3 + 24 NH4Cl + 19 H2CO3 = 24 C13H16ClNO + 33 CH3COCH3 Balanced equation:
2 C6H5CH3 + 4 CH3COCH3 + Cl2 = 2 C13H16Cl + 4 H2O Balanced equation:
26 C6H5CH3 + -1.3816108750891E-15 CH3COCH3 + 7 Cl2 + 8 H2 = 14 C13H16Cl
Reaction type: synthesis

L

Lapiz Lazuli gem: Na7Al12O24[SO4]2. 7NaCl+Al(OH)3+4Al+2H2SO4 600 degrees f